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Heat does not flow spontaneously from a cool body to a hotter body.
The entropy of an isolated system (e.g. the universe) increases in the course of a spontaneous change.
?Suniverse = ?Ssystem + ?Ssurroundings , where ?Suniverse > 0 for a spontaneous process
Entropy
Conceptual definition:
Is a measure of how much energy is in the system, and how spread out this energy is in the system.
Statistical definition:
Entropy is proportional to the number of microstates the components of a system can access without changing the system macroscopically.
Examples of microstates include molecular speeds, bond rotations, vibrations, molecular structures, etc
Thermodynamic definition:
dS=dqrevT
d
S
=
d
q
r
e
v
T
Entropy equations for an isothermal change in volume of an ideal gas:
?Ssys=nRln(V2V1)
?
S
s
y
s
=
n
R
ln
V
2
V
1
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